Research progress on petroleum coke for mercury removal from coal-fired flue gas

Mercury pollution from coal combustion has attracted widespread attention. Petroleum coke (PC), a by-product from petrochemical industry, is a potential substance to replace activated carbon mercury removal adsorbent. Most of the published articles on PC-based mercury removal adsorbent are reviewed in this work. It shows raw PC has little mercury removal ability (5%). Pyrolysis can increase mercury removal ability of PC with limited improvement effect (below 60%). KOH activation benefits for pore structure development but results in sulfur removal. SO2 activation improve surface pore structure and sulfur content of the PC, which can realize Hg0 capture rate higher than 90%. The mercury species on the used SO2 impregnated PC are mainly HgSblack and HgSred. The mechanochemical liquid bromine modified PC can achieve very high mercury removal efficiency of above 98%. However, the effects of pyrolysis, SO2 activation, and mechanochemical modification parameters on the surface physical-chemical properties especially sulfur forms of PC, as well as the modification mechanism and mercury removal mechanism need to be further studied. Mechanochemically modified PC is a promising mercury removal adsorbent. This work hopes to provide guidance for the development of high-performance PCbased mercury removal adsorbents and its industrial application.

Automated summary

Petroleum coke is a potential substance to replace activated carbon for mercury removal. Pyrolysis and SO2 activation can enhance the mercury removal ability of petroleum coke, especially mechanochemical modification can achieve very high mercury removal efficiency. Further studies are needed to explore the impact of different parameters on the properties of petroleum coke and the mechanisms of modification and mercury removal.