4.7 Article

Effect of molecular carbon structures on the evolution of the pores and strength of lignite briquette coal with different heating rates

Journal

FUEL
Volume 307, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2021.121917

Keywords

Briquette coal; Molecular carbon structures; Pores; Strength; Heating rate

Funding

  1. National Science and Technology Major Project of China [2016ZX05044002]
  2. National Natural Science Foundation of China [52074047, 51874055, 51904044]
  3. Natural Science Foundation of Chongqing, China [cstc2019jcyj-bshX0073]
  4. Chongqing Special Postdoctoral Science Foundation [XmT2018005]

Ask authors/readers for more resources

In this study, the influence of heating rate on the structure, pore, and carbon molecular structure of briquette coal (BC) was examined using various analytical methods. Results showed that a heating rate of 5 degrees C/min is suitable for BC preparation, providing an excellent alternative raw material for large-scale physical simulation experiments.
Briquette coal (BC) is the material produced from coal and gas outburst experiments. Preparing BC via the heating and pressure method can improve its low mechanical strength in physical simulation tests and gas outbursts while increasing experimental reliability. However, the influence of heating rate on the mechanical properties and microstructure of BC and the reasons underlying the evolution of its mechanical strength analyzed in terms of carbon molecular structure still need to be further studied. In this study, we developed an experimental system to prepare BC. The influence of the pore and carbon molecular structure on the BC uniaxial compressive strength was examined via a rock mechanics test system, scanning electron microscopy, nuclear magnetic resonance, specific surface area analysis, X-ray diffraction, and Fourier transform infrared spectroscopy. The results indicated that when the heating rate was increased from 3 to 6 degrees C/min, the briquette structure changed from looser smooth sheets to rough agglomerates of coal. The pore types observed after four different heating treatments (3, 4, 5, and 6 degrees C/min) on briquette samples were primarily micropores and mesopores. At 5 degrees C/min, the number of micropores in the briquette sample were significantly higher than that observed in other samples. All samples exhibited similar adsorption curves as those of inverted S-type coal samples, which can be regarded as a combination of Type IV isotherms. With increasing heating rates, the La and Lc first increased and then decreased, with a decrease in Aar/Aal, whereas Hal/H and CH2/CH3 increased. The strength of coal samples under the increasing heating rates were 5.62, 6.43, 7.07, and 5.99 MPa, respectively. The heating rate of 5 degrees C/min was found to be the appropriate heating rate for briquette preparation. These results can provide an excellent alternative raw material required for large-scale physical simulation experiments for the prevention and control of coal and gas outbursts.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available