Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2021, Issue 48, Pages 6768-6772Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202101178
Keywords
Amides; Amines; C-H activation; Copper; Oxidation
Categories
Funding
- National Natural Science Foundation of China [21861031, 21362025]
- Institute local cooperation project of Chinese Academy of Engineering [2019NXZD1]
- Key Research and Development project of Ningxia [2019BDE03002, 2021BEG02001, 2021BEE03003]
- National First-rate Discipline Construction Project of Ningxia (Chemical Engineering and Technology) [NXYLXK2017A04]
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A novel tandem N-dealkylation and N-methyl aerobic oxidation of tertiary aromatic amines to N-arylformamides using copper and TEMPO has been developed, providing an alternative synthetic route from N-methylarylamines to N-arylformamides.
A novel tandem N-dealkylation and N-methyl aerobic oxidation of tertiary aromatic amines to N-arylformamides using copper and TEMPO has been developed. This methodology suggested an alternative synthetic route from N-methylarylamines to N-arylformamides.
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