Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2021, Issue 45, Pages 6111-6114Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202101335
Keywords
Cyclobutanones; Enones; Fe-catalyst; Ketones; Ring-opening
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Funding
- Jilin Provincial 13th Five Year Plan Science and Technology Project [JJKH20181022KJ]
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An unprecedented Fe-catalyzed ring-opening reaction of simple cyclobutanones has been developed, allowing for the synthesis of conjugated enones with good functional group tolerance in high yields under mild conditions. Product derivatization and gram-scale experiments further demonstrated the synthetic utility of the reaction.
An unprecedented Fe-catalyzed ring-opening reaction of simple cyclobutanones is developed, which provides access to conjugated enones with good functional group tolerance in high yields under mild conditions. The product derivatization and gram-scale experiments further showcased the synthetic utility of the reaction.
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