4.7 Article

Pesticide concentrations in agricultural storm drainage inlets of a small Swiss catchment

Journal

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
Volume 29, Issue 29, Pages 43966-43983

Publisher

SPRINGER HEIDELBERG
DOI: 10.1007/s11356-022-18933-5

Keywords

Storm drainage inlets; Hydraulic shortcuts; Field study; Agricultural runoff; Surface runoff; Spray drift; Pesticide concentrations; Pesticide transport pathways

Funding

  1. Lib4RI-Library for the Research Institutes within the ETH Domain: Eawag, Empa, PSI WSL
  2. Swiss Federal Office of the Environment [00.0445.PZ I P293-1032]

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This study validates the impact of agricultural storm drainage inlets on surface runoff and pesticide transport through field measurements. The results show that these inlets can significantly increase pesticide concentrations in surface waters and transport substantial pesticide loads into streams.
Agricultural pesticides transported to surface waters pose a major risk for aquatic ecosystems. Modelling studies indicate that the inlets of agricultural storm drainage systems can considerably increase the connectivity of surface runoff and pesticides to surface waters. These model results have however not yet been validated with field measurements. In this study, we measured discharge and concentrations of 51 pesticides in four out of 158 storm drainage inlets of a small Swiss agricultural catchment (2.8 km(2)) and in the receiving stream. For this, we performed an event-triggered sampling during 19 rain events and collected plot-specific pesticide application data. Our results show that agricultural storm drainage inlets strongly influence surface runoff and pesticide transport in the study catchment. The concentrations of single pesticides in inlets amounted up to 62 mu g/L. During some rain events, transport through single inlets caused more than 10% of the stream load of certain pesticides. An extrapolation to the entire catchment suggests that during selected events on average 30 to 70% of the load in the stream was transported through inlets. Pesticide applications on fields with surface runoff or spray drift potential to inlets led to increased concentrations in the corresponding inlets. Overall, this study corroborates the relevance of such inlets for pesticide transport by establishing a connectivity between fields and surface waters, and by their potential to deliver substantial pesticide loads to surface waters.

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