4.7 Article

Integrating water quality index, GIS and multivariate statistical techniques towards a better understanding of drinking water quality

Journal

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
Volume 29, Issue 18, Pages 26860-26876

Publisher

SPRINGER HEIDELBERG
DOI: 10.1007/s11356-021-17594-0

Keywords

Principal component analysis; Hierarchical cluster analysis; Discriminant analysis; Entropy; Kriging; Semivariogram

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Groundwater is a crucial component of accessible water resources worldwide but faces issues of depletion and degradation due to urbanization, industrialization, and intensive agriculture. Analysis of groundwater samples in Mewat district revealed poor water quality in majority of the samples. The study also highlighted spatial distribution, composition, and quality disparities in groundwater.
Groundwater is considered as an imperative component of the accessible water assets across the world. Due to urbanization, industrialization and intensive farming practices, the groundwater resources have been exposed to large-scale depletion and quality degradation. The prime objective of this study was to evaluate the groundwater quality for drinking purposes in Mewat district of Haryana, India. For this purpose, twenty-five groundwater samples were collected from hand pumps and tube wells spread over the entire district. Samples were analyzed for pH, electrical conductivity (EC), total dissolved solids (TDS), total hardness (TH), turbidity, total alkalinity (TA), cations and anions in the laboratory using the standard methods. Two different water quality indices (weighted arithmetic water quality index and entropy weighted water quality index) were computed to characterize the groundwater quality of the study area. Ordinary Kriging technique was applied to generate spatial distribution map of the WQIs. Four semivariogram models, i.e. circular, spherical, exponential and Gaussian were used and found to be the best fit for analyzing the spatial variability in terms of weighted arithmetic index (GWQI) and entropy weighted water quality index (EWQI). Hierarchical cluster analysis (HCA), principal component analysis (PCA) and discriminant analysis (DA) were applied to provide additional scientific insights into the information content of the groundwater quality data available for this study. The interpretation of WQI analysis based on GWQI and EWQI reveals that 64% of the samples belong to the poor to very poor bracket. The result for the semivariogram modeling also shows that Gaussian model obtains the best fit for both EWQI and GWQI dataset. HCA classified 25 sampling locations into three main clusters of similar groundwater characteristics. DA validated these clusters and identified a total of three significant variables (pH, EC and Cl) by adopting stepwise method. The application of PCA resulted in three factors explaining 69.81% of the total variance. These factors reveal how processes like rock water interaction, urban waste discharge and mineral dissolution affect the groundwater quality.

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