Pongamia pinnata biodiesel production using cobalt doped ZnO nanoparticles-An analytical study

Karanja is second most popular non-edible oil, in Indian sub-continent, for Biodiesel production; with current plantation, almost 55,000 ton/year of oil can be extracted. Also, studies in past two decades have elucidated that use of heterogeneous solid catalyst has been commercially most viable, economical, produces almost pure biodiesel, easy to use, recycle and environment friendly. In this paper, we have used cobalt doped zinc oxide (CZO) nanoparticles for dual step esterification-transesterification processes, which has not been studied for Karanja oil, additionally, the detailed analytical study such as X-ray diffraction, field emission scanning electron microscope, Brunauer-Emmett-Teller and energy-dispersive analysis of X-rays on catalyst unavailable in literature, has also been incorporated here. The CZO particles are synthesized using co-precipitation method and yields particles of size similar to 75 nm, the reusability of catalyst is also included. The optimum process parameters where experimentally determined and compositional analysis of oil and biodiesel is done using Fourier transformed infrared. The economic and technical aspects of CZO synthesis, the benefits of easy separation of glycerol and reduced impurities in final product, make this process commercially more suitable for Karanja oil biodiesel synthesis, and study will promote use of CZO nanoparticles for other oil biodiesel production too. Result shows that under optimized condition of transesterification, 1:25 M ratio of oil:methanol, 0.3 wt% catalytic concentration, 70 degrees C reaction temperature, 180 min time of reaction and 500 rpm of stirring speed fatty acid methyl ester (biodiesel) conversion was 98.5 +/- 0.5%.

Automated summary

This paper investigates the use of CZO nanoparticles for esterification-transesterification processes of Karanja oil, and includes a detailed analysis of the catalyst. The results show that this method is commercially viable and economical for biodiesel synthesis from Karanja oil.