Journal
ENERGY & FUELS
Volume 36, Issue 2, Pages 922-931Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.energyfuels.1c02523
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Funding
- Helmholtz
- OCPC (The Office of China Postdoctoral Council)
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The study found that using DCM in the continuous HTL process can increase the biocrude yield, with 350 degrees Celsius being the optimal operating temperature. The AP contains more nitrogen and other ions, which is advantageous for nutrient recovery. AP treated with activated carbon absorption purification can enhance algae growth.
Dichloromethane (DCM) is a solvent commonly used in laboratories for microalgae hydrothermal liquefaction (HTL) product separation. The addition of DCM would lead to an overestimation effect of biocrude yield and diminish biocrude quality. However, it is currently not clear to what extent this overestimation effect will impact a continuous HTL process. In this study, Chlorella vulgaris microalgae was processed in a continuous stirred tank reactor at different temperatures (300, 325, 350, 375, and 400 degrees C) at 24 MPa for 15 min holding time. Two separation methods were applied to investigate the effect of using DCM in a cHTL product separation procedure in terms of product yield, biocrude elemental content, and aqueous product (AP) composition. Subsequently, the feasibility of reusing AP for algae cultivation has been evaluated. Results suggest that 350 degrees C is the optimal temperature for cHTL operation, leading to the highest biocrude yield, and an average increase in biocrude yield of 9 wt % was achieved when using DCM in cHTL product separation. Within the temperature range investigated, an average biocrude yield estimation can be proposed by yield(non-DCM) approximate to 0.818 x yield(DCM). The AP has been characterized by total organic carbon and total nitrogen, high-performance liquid chromatography, and inductively coupled plasma optical emission spectroscopy. Results show that at 350-375 degrees C more nitrogen and other ions were directed into the AP, which could be advantageous in nutrient recovery. With the help of optical density testing, algae was shown to exhibit a better growth using AP with activated carbon absorption purification treatment as compared to the standard medium. The recovery of water and nutrients from the HTL-AP could improve the economics of a microalgae biorefinery process.
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