4.7 Review

Functional Biochar Synergistic Solid/Liquid-Phase CO2 Capture: A Review

Journal

ENERGY & FUELS
Volume 36, Issue 6, Pages 2945-2970

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.energyfuels.1c04372

Keywords

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Funding

  1. National Natural Science Foundation of China [52006047]
  2. Fundamental Research Funds for the Central Universities [FRFCU5710051521]
  3. China Postdoctoral Science Foundation [2020M670908]
  4. Heilongjiang Provincial Postdoctoral Science Foundation [LBH-Z19151]
  5. Foundation of State Key Laboratory of High-Efficiency Utilization of Coal and Green Chemical Engineering [2021-K05]

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This article reviews the existing post-combustion CO2 capture solutions, with a focus on liquid-phase and solid-phase CO2 capture technologies. The author proposes the concept of biochar-functionalized crosslinking synergistic ammonia CO2 capture technology, which has practical significance for the utilization of biomass waste and reduction of CO2 emissions.
Nowadays, global warming is becoming more and more serious, while CO2 capture technologies have emerged endlessly, with methods of solid-phase CO2 capture for physical adsorption and liquidphase CO2 capture for chemical absorption. Biochar has been widely used to achieve CO2 sequestration and emission reduction as a result of its wide range of precursor sources, strong adsorption, and rich surface functional groups. It reviews the existing post-combustion CO2 capture solutions, focusing on the analysis of CO2 capture technologies based on liquid-phase ammonia/monoethanolamine and solid-phase carbonbased materials. The former (liquid phase) is with limitation of capture efficiency as a result of strong volatility and thermal degradation, while the latter (solid phase) is accompanied by limited CO2/N-2 selectivity. The realization of synergy between the two would learn from each other's strengths to improve the CO2 adsorption ability. The review puts forward the concept of biochar-functionalized crosslinking synergistic ammonia CO2 capture technology, which not only broadens the idea of multi-level utilization of biochar, significantly improving the liquid-phase (ammonia) CO2 capture efficiency, but also has practical significance for the utilization of biomass waste and reduction of CO2 emissions.

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