Journal
ENERGY & ENVIRONMENTAL SCIENCE
Volume 15, Issue 1, Pages 320-333Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ee01832a
Keywords
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Funding
- Natural Science Foundation of China [21971014, 21672023]
- National Key Research and Development Program of China [2018YFA0901800]
- Thousand Youth Talents Plan of China
- BIT Teli Young Fellow Recruitment Program
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The synthesis of two new hetero-dihalogenated terminals with a fluorine/chlorine or fluorine/bromine pair, along with three NFAs incorporating these terminals, led to the achievement of high-performance OSCs. The presence of a fluorine/chlorine hetero-dihalogenated terminal resulted in the most planar molecular geometry, shortest intermolecular packing distance, and largest pi-pi electronic coupling among the acceptors, leading to improved crystallinity, phase separation, charge mobility, and recombination for enhanced power conversion efficiency of up to 17.52%.
Despite the dihalogenation of terminals being an effective strategy to produce efficient nonfullerene acceptor (NFA)-based organic solar cells (OSCs), hetero-dihalogenated terminals are quite difficult to prepare. Here, we synthesized, for the first time, two new hetero-dihalogenated terminals (FCl-IC and FBr-IC) with a fluorine/chlorine or fluorine/bromine pair at one terminal and three NFAs (Y-BO-FCl, Y-BO-FBr, and Y-BO-ClBr) with three hetero-dihalogenated terminals (FCl-IC, FBr-IC, and ClBr-IC) using a general process for OSCs, respectively. A neat film of Y-BO-FCl presents a slightly lower energy level in comparison to those of Y-BO-FBr and Y-BO-ClBr. We, for the first time, obtained single crystals of hetero-dihalogenated NFAs. On going from Y-BO-ClBr single crystals to fluorinated acceptor single crystals, the crystal systems and intermolecular packing motifs were significantly improved. The crystallographic and theoretical analysis indicate that Y-BO-FCl exhibits the most planar molecular geometry, the shortest intermolecular packing distance and Largest pi-pi electronic coupling among these acceptors. Moreover, PM6:Y-BO-FCl blend films present more ordered face-on orientation crystallinity, more suitable fiber-Like phase separation, higher and more balanced charge mobility, and weaker charge recombination in comparison with those of PM6:Y-BO-FBr and PM6:Y-BO-ClBr. As a result, a performance of up to a remarkable power conversion efficiency of 17.52% with an enhanced FF value of ca. 78% was achieved in binary Y-BO-FCl: PM6 devices compared to those of PM6:Y-BO-FBr (16.47%) and PM6:Y-BO-ClBr (13.61%), which to date is the highest efficiency for a hetero-halogenated NFAs-based OSC. Our investigations demonstrate that a fluorine/chlorine hetero-dihalogenated terminal represents a new and effective synergistic strategy to induce significant differences in single crystals and produce high-performance hetero-halogenated NFA-based OSCs.
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