Journal
ENERGY
Volume 238, Issue -, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.energy.2021.121767
Keywords
Oxygen vacancies; Co9S8@NiCo-LDH nanotube Arrays; Battery-capacitor hybrid supercapacitors; Flexible
Categories
Funding
- National Natural Science Foun-dation of China [51872002, 21771001]
- key research and development projects in Anhui province [202004a07020026]
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By introducing oxygen vacancies, the electrochemical energy storage performance of Co9S8@NiCo-LDH NTAs is enhanced, resulting in higher specific capacity and improved cyclic stability.
In this work, rich oxygen vacancies are obtained in Co9S8@NiCo-LDH core-shell nanotube arrays (NTAs), which boost its electrochemical energy storage performance. The flexible carbon cloth (CC) supported Co9S8@NiCo-LDH NTAs are synthesized by situ growth and electrodeposition method. After reacting with NaBH4, the rich oxygen vacancies are generated in NiCo-LDH nanosheets to obtain Co9S8@oxygen vacancies-NiCo-LDH NTAs (Co9S8@OV-NiCo-LDH NTAs). These oxygen vacancies increase the charge transfer rate in the multi-level redox processes and make the electrochemical performance improve sharply. At a current density of 0.5 A g(-1), the mass specific capacity of Co9S8@OV-NiCo-LDH NTAs is up to 1335 C g(-1), which is more than four times higher than that of the untreated Co9S8@NiCo-LDH NTAs. In addition, with the prepared Co9S8@OV-NiCo-LDH core-shell NTAs as a positive electrode, along with the negative electrode of activated carbon (AC), a high-performance flexible all-solid battery-capacitor hybrid supercapacitors (HSC) device is assembled. The maximum energy density is up to 101.1 Wh kg(-1) when the power density is 800 W kg(-1). (C) 2021 Elsevier Ltd. All rights reserved.
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