4.5 Article

Application Properties of ZnO and AZO Thin Films Obtained by the ALD Method

Journal

ENERGIES
Volume 14, Issue 19, Pages -

Publisher

MDPI
DOI: 10.3390/en14196271

Keywords

AZO thin films; ALD technique; optical properties; structural properties; electrical parameters

Categories

Funding

  1. Polish Ministry of Science and Higher Education under subvention funds of the Department Institutional Review Board Statement of Electronics of AGH University of Science and Technology (AGH) [16.16.230.434]
  2. National Centre for Research and Development project [TECHMATSTRATEG1/347012/NCBR/2017, TECHMATSTRATEG1/347431/14/NCBR/2018]

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The study explored the deposition of ZnO and AZO films on silicon and glass substrates using the ALD method, with a focus on their applications in photovoltaics. Structural, optical, and electrical investigations were conducted to understand the properties of the films, and the relationships between samples doped with different Al fractions were discussed.
The thin layers of ZnO and ZnO: Al (Al doped zinc oxide-AZO) were deposited by the atomic deposition layer (ALD) method on silicon and glass substrates. The structures were deposited using diethylzinc (DEZ) and deionized water as zinc and oxygen precursors. A precursor of trimethylaluminum (TMA) was used to introduce the aluminum dopant. The present study of ALD-deposited ZnO and AZO films was motivated by their applications in photovoltaics. We attempted to expose several properties of such films. Structural, optical (including ellipsometric measurements) and electrical investigations were performed. We discussed the relations between samples doped with different Al fractions and their properties.

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