4.5 Article

A Comparison of Four Different Electrode Matrices on the Performance of Amperometric Hydrogen Peroxide (Bio)Sensors

Journal

ELECTROANALYSIS
Volume 34, Issue 7, Pages 1092-1102

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/elan.202100469

Keywords

Amperometric (bio)sensor; hydrogen peroxide; carbon nanotubes; zinc oxide nanoparticles; ionic liquid; prussian blue

Funding

  1. Tekirda Namk Kemal University Scientific Research Projects Coordination Unit [NKUBAP.01, 19.202]

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A comparison of four different (bio)sensor designs in H2O2 determination showed that the (bio)sensor based on HRP/IL-MWCNT-ZnONP/GCE exhibited the best analytical characteristics.
A comparison of the analytical performances of four different (bio)sensor designs in H2O2 determination is discussed. The (bio)sensor designs developed were based on the use of (i) multiwalled carbon nanotubes (MWCNT), zinc oxide nanoparticles (ZnONP), prussian blue (PB); (ii) MWCNT, ZnONP, PB and ionic liquid (IL); (iii) MWCNT, ZnONP and horseradish peroxidase (HRP) and (iv) MWCNT, ZnONP, HRP and IL modified glassy carbon electrode (GCE). A performance comparison of (bio)sensors showed that the one based on HRP/IL-MWCNT-ZnONP/GCE showed the best analytical characteristics with a linear dynamic range of 9.99x10(-8)-7.55x10(-4) M, detection limit of 1.37x10(-8) M and sensitivity of 17.00 mu A mM(-1).

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