4.7 Article

Solution-processable donor-π-acceptor derivatives for high-performance electronic memristors

Journal

DYES AND PIGMENTS
Volume 194, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2021.109576

Keywords

D-pi-A systems; Physical property; Electronic memristor

Funding

  1. National Natural Science Foundation of China [21672051, 22008164]
  2. Natural Science Foundation of Hebei Province for Distinguished Young Scholar [B2017201072]
  3. Natural Science Foundation of Hebei Province [B2020201044, BK20190939]
  4. Key Research Projects of Science and Technology in Universities of Hebei Province [ZD2020128]
  5. talent training project of Hebei Province [A201902006]
  6. Natural Science Foundation of the Jiangsu Higher Education Institutions of China [19KJB150018]

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By synthesizing and fully characterizing two novel small donor-pi-acceptor derivatives, it was found that the device based on 5 exhibited wider memory windows, higher ON/OFF ratio, and excellent bipolar resistive switching behavior compared to the device based on 3.
Two novel small donor-pi-acceptor derivatives (D-pi-A, 3 and 5) containing aromatic amine as a donor and naphthalimide as an acceptor have been synthesized and fully characterized. The derivatives were selected as active layers in the fabrication of solution-processable electronic resistive memory devices. The experimental results indicated that the 5-based device exhibited wider memory windows, higher ON/OFF ratio and excellent bipolar resistive switching behavior compared with the 3-based device. In addition, detailed analyses of electrical properties, intramolecular charge transfer in molecules 3 and 5, and surface morphology of the as-prepared devices were carried out to realize the boosting resistive switching response.

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