Journal
DYES AND PIGMENTS
Volume 198, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2021.109986
Keywords
MoS2/ZnPc composite; Optical limiting; Nonlinear optical properties; Z-scan
Funding
- National Natural Science Foundation of China [61705063, 61841504]
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Zinc phthalocyanine was used to functionalize sulfur vacancies of MoS2, leading to the synthesis of MoS2/ZnPc composite. This composite showed higher third order nonlinear absorption coefficients and lower limiting thresholds compared to individual MoS2 or ZnPc, due to a combination of various nonlinear absorption mechanisms.
Zinc phthalocyanine carrying sulfenyl and 6-sulfydryl linkers was firstly used to functionalize with sulfur vacancies MoS2. The synthesized MoS2/ZnPc composite was further prepared to be PVA (polyvinyl alcohol) thin films by a drop coating method. The microscopic structures and photophysical properties of novel MoS2/ZnPc composite were characterized. A series of analysis results indicate that zinc phthalocyanine with sulfenyl and 6-sulfydryl linkers is loaded to sulfur vacancies of MoS2 by ligand conjugation. The third order nonlinear optical properties of MoS2/ZnPc composite were studied by an open aperture Z-scan technique at 532 nm with 4 ns laser pulses width. In comparison with individual MoS2 or ZnPc, whether MoS2/ZnPc solution or MoS2/ZnPc/PVA film sample possesses larger third order nonlinear absorption coefficients (beta) and lower limiting thresholds (F-50). It can be ascribed to a combination of different NLO absorption mechanisms for MoS2/ZnPc composite, including one-photon absorption, two photon absorptions and nonlinear scattering of MoS2, triplet excited state absorption of ZnPc, nonlinear scattering of MoS2/ZnPc and the photo-induced electron transfer or energy transfer (PET/ET) process between MoS2 and ZnPc moieties.
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