Journal
DALTON TRANSACTIONS
Volume 51, Issue 1, Pages 48-52Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1dt03347f
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- JSPS KAKENHI [JP21K05103]
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The crystalline-state photochromism of a new organorhodium dinuclear complex was investigated through single-crystal X-ray diffraction experiments. An intriguing reversible conformational change of the n-methoxypropyl moiety was observed during a thermal back-reaction.
The crystalline-state photochromism of a new organorhodium dinuclear complex having n-methoxypropyltetramethylcyclopentadienyl (eta(5)-C(5)Me(4)n-C3H6OCH3) and photoresponsive dithionite (mu-O2SSO2) ligands was investigated directly by performing single-crystal X-ray diffraction experiments; a reversible conformational change of the n-methoxypropyl moiety was intriguingly observed during the course of a thermal back-reaction.
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