Journal
CRYSTENGCOMM
Volume 24, Issue 13, Pages 2370-2382Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ce01633d
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Funding
- National Natural Science Foundation of China [22061019, 21761012]
- Natural Science Foundation of Jiangxi Province [20202ACBL213001, 20192BAB203001]
- Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry [20212BCD42018]
- Youth Jinggang Scholars Program in Jiangxi Province [QNJG2019053]
- Double Thousand Talents Program in Jiangxi Province [jxsq2019201068, jxsq2020101087]
- Doctor's Starting Research Foundation of Jiangxi University of Science and Technology [205200100536]
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This review summarizes the synthesis, structures, and magnetism of Gd(iii)-based inorganic polymers, metal-organic frameworks, and coordination polymers, with a focus on the synthetic strategy towards molecular magnetorefrigerants. The conclusions and perspectives for Gd(iii)-based magnetorefrigerants are presented, providing new insights for further development in this promising field.
As alternatives to the expensive and increasing shortage of He-3 for ultralow-temperature refrigeration, molecule-based magnetorefrigerant materials have attracted much attention in past decades. Among these, Gd(iii)-based inorganic polymers, metal-organic frameworks, and coordination polymers with large magnetic densities and weak magnetic interactions have become a research focus. In this review, the synthesis, structures, and magnetism of Gd(iii)-based inorganic polymers, metal-organic frameworks, and coordination polymers based on various inorganic and organic ligands are summarized and discussed, with an emphasis on the synthetic strategy towards molecular magnetorefrigerants with good stability and a large magnetocaloric effect. In addition, the conclusions and perspectives for Gd(iii)-based magnetorefrigerants are presented and new insights for the further development of this promising area. Therefore, this review should serve as a tutorial for newcomers as well as a summary of the research progress in the field of magnetic refrigeration.
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