4.7 Article

Corrosion and passivation behavior of laser powder bed fusion produced Ti-6Al-4V in static/dynamic NaCl solutions with different concentrations

Journal

CORROSION SCIENCE
Volume 191, Issue -, Pages -

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2021.109728

Keywords

Laser powder bed fusion; Titanium; Corrosion; Oxide film; NaCl; Dynamic solution

Funding

  1. Open Foundation of Guangxi Key Laboratory of Processing for Non-ferrous Metals and Featured Materials [2021GXY-SOF03]
  2. Jiangsu Province six talent peaks project [XCL-117]
  3. ECU Postgraduate Research Scholarship

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The study found that Ti-6Al-4V forms oxide films in NaCl solutions, with film thickness increasing with Cl- concentration, and more TiO2 content in dynamic conditions. The corrosion behavior and film growth mechanisms were discussed based on electrochemical and surface characteristic measurements.
In this work, the corrosion and passivation behavior of Ti-6Al-4V produced by laser powder bed fusion (L-PBF) were investigated in different concentration of NaCl solutions under static and dynamic conditions. Oxide films including TiO2, Ti2O3, TiO were formed on L-PBF-produced Ti-6Al-4V. The film thickness increased under both test conditions with increasing the Cl- concentration, and the film contained more TiO2 in dynamic conditions under the same Cl- concentration. The mechanism of the corrosion behavior and film growth under different Cl- concentration and electrolyte conditions were discussed by the relevant electrochemical and surface characteristic measurements, e.g. Mott-Schottky analysis, X-ray photoelectron spectroscopy.

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