Journal
COORDINATION CHEMISTRY REVIEWS
Volume 448, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2021.214112
Keywords
Imido; Oxo; Metathesis; Heterometathesis; Cycloaddition; Surface Organometallic Chemistry
Categories
Funding
- Russian Science Foundation [19-73-10163]
- Ministry of Science and Higher Education of the Russian Federation
Ask authors/readers for more resources
The review summarizes literature examples of stoichiometric oxo/imido heterometathesis reactions and discusses the current progress in catalytic oxo/imido heterometathesis development, with a focus on preparing highly efficient catalysts based on silica-supported early transition metal oxo and imido complexes using Surface Organometallic Chemistry approach.
Oxo/imido heterometathesis is a class of reactions that interconvert terminal transition metal oxo and imido complexes via [2 + 2] cycloaddition/cycloreversion with heteroolefins and heterocumulenes containing oxo and imino groups. In this review we summarize the literature examples of stoichiometric oxo/imido heterometathesis reactions of imido complexes with different oxo substrates and discuss the current progress in the development of catalytic oxo/imido heterometathesis. In particular, we show how application of Surface Organometallic Chemistry approach allows preparation of highly efficient oxo/imido heterometathesis catalysts based on well-defined silica-supported early transition metal oxo and imido complexes. (C) 2021 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available