Journal
COMPOSITES PART B-ENGINEERING
Volume 225, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.compositesb.2021.109300
Keywords
Carbon fiber; polymer-matrix composites (PMCs); interface/interphase; Surface treatments
Funding
- National Natural Science Foundation of China [51603169]
- University Youth Talent Promotion Program of Shaanxi Association for Science Technology [20210405]
- Natural Science Basic Research Plan in Shaanxi Province of China [2017JQ5050]
- Natural Science Foundation of Shaanxi University of Science Technology [2016QNBJ-12]
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In this study, an innovative use of vacuum filtration approach is proposed to modify the circumferential surface of structural carbon fiber, aiming to improve the interfacial adhesion of composites by constructing a synergistic hydrogen bond network. The obtained hybrid reinforcement exhibits significantly higher interfacial shear strength compared to untreated fiber and CNF/CNT grafted fiber. The improvement is mainly attributed to the formation of dense hydrogen bonds among CNFs, PVA, and CNTs, leading to larger energy consumption at interphase, as well as the spider's web-like structure of CNF/CNT that deflects cracks and promotes stress transfer.
Herein, innovative use of vacuum filtration approach to modify the circumferential surface of structural carbon fiber is proposed for improving the interfacial adhesion of composites by constructing a synergistic hydrogenbond network on fiber surface via the utilization of carbon nanofibers (CNFs), carbon nanotubes (CNTs) and polyvinyl alcohol (PVA). The obtained hybrid reinforcement presents 123.18 MPa of interfacial shear strength, respectively 105.7% and 52.5% exceeding those of untreated fiber and CNF/CNT grafted fiber. Such dramatic improvement can be mainly assigned to the formation of dense hydrogen bonds among the richer hydroxyl groups of CNFs and PVA, and the active sites of CNTs, leading to larger energy consumption at interphase. Meanwhile, CNF/CNT assembled like the spider's web, which could deflect cracks and give rise to the gradual transition of interfacial modulus. This promotes the stress transfer and avoids the stress concentration. The vacuum filtration belongs to a facile, low-cost and eco-friendly strategy, which has been proven successful in obtaining composites with great interfacial adhesion, opening an advanced way for the surface modification of high-performance fibers.
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