Graphene oxide doped ethanol droplet combustion: Ignition delay and contribution of atomization to burning rate

Effects of graphene oxide nanomaterials addition and oxidation level on ignition delay and burning rate of ethanol droplets are experimentally investigated. Three graphene oxide samples are synthesized and characterized. Separate high-speed OH * chemiluminescence and high-speed shadowgraphy images are collected. The results suggest that increasing the loading concentration from 0 to 0.1% (by weight) generally increases the ignition delay, except for ethanol doped with the highly oxidized graphene. The results show that unlike pure ethanol droplets, atomization may occur for the doped ethanol droplets. It is demonstrated that, independent of the tested conditions, atomization occurs in the second half of the droplet lifetime. The probability density function of the atomized baby droplet diameter, initial projected velocity, and length of the projected trajectory are similar for all tested conditions and independent of the oxidation level and loading concentration of the additives. The joint probability density function calculated for the atomization-related parameters against one another suggests that the majority of the baby droplets feature a relatively short lifetime, indicating they may potentially burn inside the flame envelope. Using droplet surface regression curves versus time, the burning rate for periods in which the atomization does not occur, and for the periods that the atomization is present are estimated. The former burning rate is shown to enhance by increasing the loading concentration and reducing the oxidation level of graphene. However, supported by Fourier-Transform Infrared spectroscopy of the graphene oxide samples, it is found that a maximum increase in the latter burning rate for both loading concentrations occurs for ethanol doped with the graphene oxide that features maximum amount of infrared radiation absorption. To quantify the effect of atomization on the droplet mass loss, a conservation of mass framework is utilized, and it is shown that relatively intense atomization suppresses the droplet evaporation mass loss. Doping ethanol with graphene oxide and increasing the loading concentration from 0.01 to 0.1% enhances the overall burning rate, with a maximum enhancement of 8.4% pertaining to addition of reduced oxidized graphene oxide and for the loading concentration of 0.1%.Crown Copyright (c) 2021 Published by Elsevier Inc. on behalf of The Combustion Institute. All rights reserved.

Automated summary

The effects of graphene oxide nanomaterials addition and oxidation level on ignition delay and burning rate of ethanol droplets were investigated experimentally. The results showed that increasing the loading concentration generally increased the ignition delay, except for ethanol doped with highly oxidized graphene. It was also found that atomization may occur for the doped ethanol droplets.