Journal
CHINESE JOURNAL OF ORGANIC CHEMISTRY
Volume 42, Issue 1, Pages 1-15Publisher
SCIENCE PRESS
DOI: 10.6023/cjoc202109002
Keywords
photoredox catalysis; nickel catalysis; synergistic catalysis; alkene; alkyne; difunctionalization
Categories
Funding
- National Natural Science Foundation of China [21991123, 21971036, 21901036]
- Fundamental Research Funds for the Central Universities
- Graduate Student Innovation Fund of Donghua University [CUSF-DH-D-2020057]
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The merger of visible-light photoredox catalysis and nickel catalysis enables the construction of challenging chemical bonds under mild conditions. Photoredox/nickel dual catalysis has attracted attention in the field of catalytic difunctionalization of alkenes and alkynes, allowing for the formation of multiple chemical bonds in a single reaction, providing a mild, efficient, and selective approach.
The merger of visible-light photoredox catalysis and nickel catalysis makes it possible to forge challenging chemical bonds under mild conditions. Nevertheless, most of these transformations only construct a single carbon-carbon bond or carbon-heteroatom bond in one operation. In recent years, photoredox/nickel dual catalysis has attracted widespread attention in the field of catalytic difunctionalization of alkenes and alkynes. The synergistic cascade mode enables the construction of multiple chemical bonds in one single pot, providing a mild, efficient and selective protocol for the rapid assembly of complex structural motifs. The latest progress in the photoredox/nickel dual-catalyzed difunctionalization reactions of olefins and alkynes is summarized.
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