Journal
CHEMSUSCHEM
Volume 15, Issue 3, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.202102095
Keywords
benzyl alcohol; carboxylation; palladium; photocatalysis; visible light
Funding
- JSPS KAKENHI [15H05800, 17H06143]
- Grants-in-Aid for Scientific Research [17H06143] Funding Source: KAKEN
Ask authors/readers for more resources
A highly efficient carboxylation method of benzyl alcohol derivatives with CO2 using a palladium/iridium dual catalyst under visible-light irradiation was developed. Site-selective carboxylation between benzylic C-O and aryl C-Cl moieties could be achieved simply by changing the palladium catalyst.
A highly efficient carboxylation of benzyl alcohol derivatives with CO2 using a palladium/iridium dual catalyst under visible-light irradiation was developed. A wide range of benzyl alcohol derivatives could be employed to provide benzylic carboxylic acids in moderate to high yields. Mechanistic studies indicated that the oxidative addition of benzyl alcohol derivatives was possibly the rate-determining-step. It was also found that a switchable site-selective carboxylation between benzylic C-O and aryl C-Cl moieties could be achieved simply by changing the palladium catalyst.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available