CO2 sequestration mediated by wollastonite in anaerobic digestion of sewage sludge: From sequence batch to semi-continuous operation

This study investigated the mechanisms involved in CO2 sequestration under the sequence batch and semi continuous operation using wolla(s)tonite in sludge anaerobic digestion. Wollastonite substantially elevated CH4 content in biogas and played a role in CO2 capture. It increased biogas yield of the glucose due to pH buffering effect but did not increase that of the hydrolysate from thermal alkali pretreated sludge. Under the semi-continuous operation, wollastonite improved the CO2 sequestration, but decreased the biogas yield from 166 to 24 mL/g soluble chemical oxygen demand, since seemingly wollastonite residues inhibited microbes in the sludge. However, the use of dialysis bags to wrap wollastonite offset the negative impact of the wollastonite residues in the sludge, thereby increased biogas yield. The present study is conducive to understanding the mechanisms involved in and proving the feasibility of the CO2 sequestration using wollastonite in sludge anaerobic digestion and its impacts on long-term operation. Consequently, the findings of the study provide key parameters and useful guidelines for scaling up and wollastonite application in anaerobic digestion of sewage sludge.

Automated summary

The study showed that wollastonite significantly affected biogas production in sludge anaerobic digestion, increasing methane content but potentially inhibiting microbes. Wrapping wollastonite in dialysis bags can offset the negative impact of wollastonite residues and enhance biogas production.