Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 17, Issue 8, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.202200072
Keywords
Silver-thiolate cluster; Decatungstate; Anion template; Luminescence; Photocatalytic activity
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Funding
- 61st batch of China Postdoctoral Science Foundation [2017M611296]
- Scientific Research Fund of Liaoning Provincial Education Department [L2020039, LJKZ0397]
- National Natural Science Foundation of China [91961110]
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A new silver thiolate cluster containing a [W10O32](6-) template was synthesized through a one-pot method. The [W10O32](6-) template transformed from WO42- polyoxoanion through self-assembly. The interaction between the reduced template and silver-oxygen contributes to the formation of the Ag-44 nanowheel. The luminescence, photocatalytic activity, and electrochemistry properties of the cluster were studied.
Compound [Ag-44(W10O32)((SBu)-Bu-t)(24)(CF3COO)(8)](CF3COO)(6) . 6H(2)O (1) was synthesized through a one-pot method. This is the first case of isolating a new silver thiolate cluster containing a [W10O32](6-) template which transforms from WO42- polyoxoanion through a self-assembly process. The anionic nature of the reduced [W10O32](6-) template and the effective silver-oxygen interaction contribute to the formation of the Ag-44 nanowheel in 1. The luminescence, photocatalytic activity and electrochemistry properties of 1 were studied.
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