Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 17, Issue 5, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.202101345
Keywords
amination; alkoxysilane; silver; azodicarboxylate; arylamine
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Funding
- Hubei Provincial Department of Education Foundation [D20201405]
- JSPS KAKENHI [JP21H01934]
- Sumitomo Foundation
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A facile and efficient AgF-mediated electrophilic amination of alkoxyarylsilanes with azodicarboxylates has been developed. The reaction proceeds under green and mild conditions, generating aryl hydrazines.
A facile and efficient AgF-mediated electrophilic amination of alkoxyarylsilanes with azodicarboxylates was developed. The reaction proceeds in green solvent under simple and mild conditions to generate the corresponding aryl hydrazines. AgF acts both as a stoichiometric fluoride source and a reagent for transmetalation to the arylsilver intermediate that eventually reacts with azodicarboxylates to provide aryl hydrazines.
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