4.6 Article

Enhanced Surface Kinetics and Charge Transfer of BiVO4 Photoanodes by Rh2O3 Cocatalyst Loading for Improved Solar Water Oxidation

Journal

CHEMISTRY-AN ASIAN JOURNAL
Volume 17, Issue 5, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.202101359

Keywords

Photoelectrochemical water oxidation; BiVO4; Rh2O3; Cocatalyst

Funding

  1. National Natural Science Funds for Distinguished Young Scholars [51725201]
  2. International (Regional) Cooperation and Exchange Projects of the National Natural Science Foundation of China [51920105003]
  3. Innovation Program of Shanghai Municipal Education Commission [E00014]
  4. Science and Technology Commission of Shanghai Municipality [21DZ1207101, 19YF1411600]
  5. National Natural Science Foundation of China [51902105]
  6. Fundamental Research Funds for the Central Universities
  7. Shanghai Engineering Research Center of Hierarchical Nanomaterials [18DZ2252400]

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The Rh2O3/BiVO4 composite photoanode demonstrates enhanced surface reaction kinetics and charge transfer efficiency, resulting in a significantly higher photocurrent density and lower onset potential compared to pristine BiVO4.
A Rh2O3/BiVO4 composite photoanode exhibits enhanced surface reaction kinetics and charge transfer efficiency, enabling a photocurrent density of ca. 3.5 mA/cm(2) at 1.23 V (vs. RHE), which is about 3.89 times higher than that of the pristine BiVO4, with a lower onset potential of 0.29 V (vs. RHE).

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