Mn12-Acetate Complexes Studied as Single Molecules

The phenomenon of single molecule magnet (SMM) behavior of mixed valent Mn-12 coordination clusters of general formula [(Mn8Mn4O12)-Mn-III-O-IV(RCOO)(16)(H2O)(4)] had been exemplified by bulk samples of the archetypal [(Mn8Mn4O12)-Mn-III-O-IV(CH3COO)(16)(H2O)(4)] (4) molecule, and the molecular origin of the observed magnetic behavior has found support from extensive studies on the Mn-12 system within crystalline material or on molecules attached to a variety of surfaces. Here we report the magnetic signature of the isolated cationic species [Mn12O12(CH3COO)(15)(CH3CN)](+) (1) by gas phase X-ray Magnetic Circular Dichroism (XMCD) spectroscopy, and we find it closely resembling that of the corresponding bulk samples. Furthermore, we report broken symmetry DFT calculations of spin densities and single ion tensors of the isolated, optimized complexes [Mn12O12(CH3COO)(15)(CH3CN)](+) (1), [Mn12O12(CH3COO)(16)] (2), [Mn12O12(CH3COO)(16)(H2O)(4)] (3), and the complex in bulk geometry [(Mn8Mn4O12)-Mn-III-O-IV(CH3COO)(16)(H2O)(4)] (5). The found magnetic fingerprints - experiment and theory alike - are of a remarkable robustness: The Mn-4(IV) core bears almost no magnetic anisotropy while the surrounding Mn-8(III) ring is highly anisotropic. These signatures are truly intrinsic properties of the Mn-12 core scaffold within all of these complexes and largely void of the environment. This likely holds irrespective of bulk packing effects.

Automated summary

In this study, the magnetic properties of isolated cationic species [Mn12O12(CH3COO)(15)(CH3CN)](+) were investigated using gas phase X-ray Magnetic Circular Dichroism spectroscopy, and found to resemble closely to that of the corresponding bulk samples. Additionally, broken symmetry DFT calculations revealed that the Mn-4(IV) core exhibits almost no magnetic anisotropy, while the surrounding Mn-8(III) ring is highly anisotropic. These intrinsic magnetic properties are largely unaffected by environmental factors, suggesting robustness in the Mn-12 core scaffold within these complexes.