Journal
CHEMISTRY OF MATERIALS
Volume 34, Issue 1, Pages 273-278Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemmater.1c03406
Keywords
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Funding
- National Research Foundation (NRF) of Korea [2016R1A5A1009405]
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A highly stable and rigid rod metal-organic framework is obtained through single-crystal-to-single-crystal transformation, with significant framework contraction and formation of infinite chains of carboxylate- and aquo-linked Zr-6 clusters. This microporous rod MOF remains stable in various solvents, including H2O, and even under harsh conditions such as strongly acidic and basic aqueous solutions at 100 degrees C.
A highly stable and rigid rod metal-organic framework (MOF) is obtained by the single-crystal-to-single-crystal transformation of a Zr-6 cluster-based MOF with highly interconnected but geometrically mismatched building blocks. The transformation results in a significant framework contraction, which comes from the formation of infinite chains of carboxylate- and aquo-linked Zr-6 clusters as a one-dimensional rod secondary building unit. The permanently microporous rod MOF is stable in a variety of solvents, including H2O, and even under very harsh conditions, such as strongly acidic and basic aqueous solutions at 100 degrees C.
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