Journal
CHEMISTRY LETTERS
Volume 51, Issue 1, Pages 38-40Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.210546
Keywords
Sodium dispersion; Birch reduction; 1,3-Dimethyl-2-imidazolidinone
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Funding
- Okayama University
- RIKEN
- KOBELCO ECO-Solutions CO., Ltd.
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The combination of a sodium dispersion in paraffin oil and 1,3-dimethyl-2-imidazolidinone enables the Birch-type reduction of a variety of arenes with high yields, selectivity, and tolerance of functionality.
An easy-to-handle sodium dispersion in paraffin oil (SD), in combination with inexpensive and environmentally benign 1,3-dimethyl-2-imidazolidinone (DMI) as an additive enables the Birch-type reduction of a variety of arenes with high yields, selectivity, and tolerance of functionality such as ether, alcohol, amine, amide, and carboxylic acid.
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