4.3 Article

Design of Dimeric Dinuclear Boron Complexes with Flexible Linkers: Aggregation-induced White-light Emission via Molecular Engineering

Journal

CHEMISTRY LETTERS
Volume 51, Issue 3, Pages 300-302

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.210794

Keywords

Boron complexes; White-light emission; Aggregation

Funding

  1. JSPS KAKENHI [JP20H04675, JP20K21212, JP21H05400]
  2. Toyota Riken Scholar Program
  3. Samco Foundation
  4. TOBE MAKI Scholarship Foundation

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The study successfully controlled the aggregation state of two new covalently bonded dinuclear boron-based dye complexes to fabricate white-light-emitting materials that exhibit blue and orange emission. One of the complexes has a photoluminescence quantum yield of 16% in the solid state, highlighting the importance of molecular engineering through the control of dye aggregation for creating novel functional materials with interesting optical properties.
The aggregation state of two new covalently bonded dinuclear boron-based dye complexes was controlled to fabricate white-light-emitting materials. The materials exhibit blue and orange emission, with a photoluminescence quantum yield of 16% for one of the complexes in the solid state. This study highlights the importance of molecular engineering through the control of dye aggregation as a fundamental technology for creating novel functional materials with interesting optical properties.

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