Journal
CHEMISTRY LETTERS
Volume 51, Issue 4, Pages 455-457Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.220008
Keywords
Heterobimetallic complex; Cobalt; Aluminium
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Funding
- JST CREST program via the Establishment of Molecular Technology towards the Creation of New Functions project [JPMJCR14L3]
- JSPS KAKENHI [JP20H00376]
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A cobalt complex ligated with a PAlP pincer ligand was synthesized and the Lewis acidity of the aluminum atom on the cobalt complex was confirmed by coordination with 4-dimethylaminopyridine (DMAP). Reactions of the cobalt complex with H2O, EtOH, i-PrOH, and t-BuOH efficiently yielded the corresponding cobalt hydride complexes.
A cobalt complex ligated with a PAlP pincer ligand was synthesized. The Lewis acidity of the aluminum atom on the cobalt complex was confirmed by coordination with 4-dimethylaminopyridine (DMAP). Reactions of the cobalt complex with H2O, EtOH, i-PrOH, and t-BuOH efficiently afforded the corresponding cobalt hydride complexes.
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