4.3 Article

Luminescent Rhenium-containing Ionic Liquid Exhibiting Photoinduced Vapochromism

Journal

CHEMISTRY LETTERS
Volume 50, Issue 10, Pages 1740-1742

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.210386

Keywords

Ionic liquid; Re complex; Vapochromism

Funding

  1. KAKENHI from the Japan Society for the Promotion of Science (JSPS) [16H04132, 20H02756]

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A luminescent ionic liquid containing a cationic rhenium tricarbonyl complex was synthesized, and UV photoirradiation of this liquid in the presence of an organic solvent vapor caused a color change and luminescence quenching via photochemical ligand exchange, enabling the photocontrol of vapochromism.
A luminescent ionic liquid containing a cationic rhenium tricarbonyl complex was synthesized. UV photoirradiation of this liquid in the presence of an organic solvent vapor caused a color change and luminescence quenching via photochemical ligand exchange, thereby enabling the photocontrol of vapochromism.

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