4.2 Review

Recent Progress in Direct DME Synthesis and Potential of Bifunctional Catalysts

Journal

CHEMIE INGENIEUR TECHNIK
Volume 94, Issue 3, Pages 240-255

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cite.202100167

Keywords

Bifunctional catalysts; Catalyst design; Dimethyl ether; Kinetic modeling; Methanol

Funding

  1. German Research Foundation (DFG) [DI 696/9-3, SCHW 478/23-3]
  2. Vector Foundation [CO2mpactDME'']
  3. Helmholtz Research Program Materials and Technologies for the Energy Transition (MTET), Topic 3: Chemical Energy Carriers''
  4. Projekt DEAL

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This review article focuses on the importance of PtX technologies in the future energy system based on renewable sources, particularly discussing the application of dimethyl ether (DME) as an intermediate in the production of CO2-neutral base chemicals. The article summarizes recent developments in methanol and direct DME synthesis, with a special emphasis on modeling and bifunctional catalysts.
PtX technologies are one major building block of the future energy system based on renewables sources. Dimethyl ether (DME) is an important PtX product that can be used as intermediate the production of CO2-neutral base chemicals. New applications lead to an increase of the global production and the optimization of the process efficiency, especially when considering decentralized synthesis. This review article puts some spotlights on recent developments in methanol and the direct DME synthesis with a special focus on the modeling and bifunctional catalyst. This study is expected to provide a foundation for future works in the field of catalysis research based on catalysts design and kinetic modeling.

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