Journal
CHEMICAL REVIEWS
Volume 121, Issue 21, Pages 13238-13341Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemrev.1c00255
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Funding
- SERB [EMR/2017/000844]
- CSIR [01(3067/21/EMR-II)]
- Education Department of Hainan Province [Hnky202135]
- Julius-Maximilians-Universitat Wurzburg
- Deutsche Forschungsgemeinschaft
- National Science Foundation [CHE-1414458]
- Natural Sciences and Engineering Council of Canada [2016-04302]
- Hainan Medical University [XRC200014]
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Organoboron reagents play a unique role in modern synthetic organic chemistry, offering unprecedented reactivity and stereocontrol. The use of first-row d-block transition metals as catalysts for the formation of carbon-boron bonds has expanded in various fields such as medicinal chemistry, agrochemistry, and materials science.
Organoboron reagents represent a unique class of compounds because of their utility in modern synthetic organic chemistry, often affording unprecedented reactivity. The transformation of the carbon-boron bond into a carbon-X (X = C, N, and O) bond in a stereocontrolled fashion has become invaluable in medicinal chemistry, agrochemistry, and natural products chemistry as well as materials science. Over the past decade, first-row d-block transition metals have become increasingly widely used as catalysts for the formation of a carbon-boron bond, a transformation traditionally catalyzed by expensive precious metals. This recent focus on alternative transition metals has enabled growth in fundamental methods in organoboron chemistry. This review surveys the current state-of-the-art in the use of first-row d-block element-based catalysts for the formation of carbon-boron bonds.
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