Journal
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
Volume 38, Issue 2, Pages 296-309Publisher
HIGHER EDUCATION PRESS
DOI: 10.1007/s40242-022-1448-8
Keywords
Ionic covalent organic framework; Design and construction; Various application; Structure-function relationship
Categories
Funding
- National Natural Science Foundation of China [22178280, 21773223]
- Natural Science Basic Research Plan in Shaanxi Province of China [2020JM-005, 2020JQ-017]
- Fundamental Research Funds for the Central Universities, China [xzy012019027]
- Fundamental Research Funds for Young Talent Support Plan of Xi'an Jiaotong University, China [HG6J001]
- 1000-Plan Program of Shaanxi Province, China
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Ionic covalent organic frameworks with crystallinity and charged sites have attracted tremendous attention. They have great potential in separation, conduction, sensing, catalysis, and energy storage. This review introduces the design, construction, and applications of ionic COFs, and explores the relationship between structure and function.
Ionic covalent organic frameworks featuring both crystallinity and charged sites have arose tremendous attention from scientific community. The adjustable textural structures, well-defined channels and abundant charged sites of ionic COFs facilitate great potential in diverse aspects, such as separation, ion conduction, sensing, catalysis and energy storage. In this review, we first introduced the design and construction of ionic covalent organic frameworks(COFs), and classified them according to the types of charged sites. We focused on the various applications of ionic COFs in diverse fields. The structure-function relationship was also explored in detail. Finally, the opportunities and challenges of ionic COFs were summarized to provide guidance for better design and application of ionic COFs.
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