4.7 Article

Extensive jarosite deposits formed through auto-combustion and weathering of pyritiferous mudstone, Smoking Hills (Ingniryuat), Northwest Territories, Canadian Arctic - A potential Mars analogue

Journal

CHEMICAL GEOLOGY
Volume 587, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.chemgeo.2021.120634

Keywords

Jarosite; Bocanne; Auto-combustion; Pyrite weathering

Funding

  1. Natural Resources Canada's Geo-Mapping for Energy and Minerals Program

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Research on the Smoking Hills in Arctic Canada has revealed striking similarities to Mars, with abundant jarosite-rich deposits and sulfate minerals formed through oxidative weathering. The formation of the Smoking Hills is mainly attributed to auto-combustion of pyritic mudstones due to oxidative weathering, generating high temperatures and sulfur minerals. Therefore, the study suggests that the deposition of metal sulfates on Mars may indicate a more habitable environment than previously thought.
Jamsite and other metal sulphates are common on Mars and are interpreted to have formed in an extreme acidic saline aqueous environment, similar to modern Earth analogues where jarosite precipitates. We examined an alternative Earth analogue, at the Smoking Hills (known as Ingniryuat by Inuvialuit), Northwest Territories, Arctic Canada. The Smoking Hills are characterised by auto-combusting pyritic mudstones of the Smoking Hills Formation in a polar desert. The Smoking Hills Formation was deposited in an outer shelf to slope marine environment, during a Late Cretaceous Ocean Anoxic Event. Oxidative weathering of this unit creates extensive jarosite-rich deposits, and banded jarosite- and phyllosilicate-rich mudstones, similar to those observed on Mars. Slumping of these mudstones exposes large masses to atmospheric oxygen leading to generation of high temperatures (sufficient to produce paralavas) through pyrite oxidation, and the subsequent formation of a diverse suite of hydrated metal-sulphate minerals. Weathered combustion sites are characterised by a simpler jarosite-rich mineralogy along with thermally-altered mudstone. Away from sites of auto-combustion (bocannes), pyrite-rich layers within the mudstone oxidise to jarosite, creating a yellow-banded appearance in outcrops. These jarosite-rich layers, similar to those observed interbedded in mudstones on Mars, reflect post depositional oxidation processes - not acidic conditions during the time of deposition. As such, this could reflect a more habitable environment than is commonly interpreted for Mars.

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