Journal
CHEMICAL ENGINEERING JOURNAL
Volume 425, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2021.130607
Keywords
NiCo2N; Hollow structure; Interconnected nanosheets; Lithium-ion batteries
Categories
Funding
- National Key Research and Development Program [2017YFA0402800]
- National Natural Science Foundation of China [U1732160]
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In this study, a stable bimetal nitride NiCo2N hollow sphere material with interconnected nanosheets shell was successfully synthesized and showed excellent electrochemical performance as an anode for lithium-ion batteries. The unique structure effectively relieves the volume change of the electrode material and shortens the diffusion distance of lithium ions, leading to high discharge capacity and good cycling stability. The electrochemical reaction mechanism of the electrodes was revealed through ex situ XRD, ex situ EIS, and ex situ HRTEM characterization.
Transition metal nitrides are of great interest for lithium storage application due to their high electrical conductivity and low voltage plateau. However, the relative cycling stability restricts their practical application. Herein, a stable bimetal nitride NiCo2N hollow sphere material with interconnected nanosheets shell was successfully synthesized via a facial solvothermal route. When used as anodes for lithium-ion batteries, the unique structure can effectively relieve the volume change of the electrode material, and shorten the diffusion distance of lithium ions during the repeated cycling processes. As a result, the NiCo2N electrode exhibits an excellent electrochemical performance. It delivers high discharge capacity of 1244.5 mAh g(-1) at a current density of 1 A g(-1) after 400 cycles, the capacity can maintain 529.4 mAh g(-1) at high current density of 5 A g(-1). Furthermore, the electrochemical reaction mechanism of the electrodes is revealed by ex situ XRD, ex situ EIS, and ex situ HRTEM characterization.
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