Journal
CHEMICAL ENGINEERING JOURNAL
Volume 422, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2021.130026
Keywords
Solar reactor; MIEC ceramic membrane; Oxygen transport; Ceria; CO2 dissociation; Solar fuel
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Funding
- French National Agency for Research (ANR, SUNFUEL project) [ANR-16-CE06-0010]
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CO2 single-step thermolysis was achieved using oxygen permeable MIEC membranes made of ceria for separate production of CO and O-2. Concentrated solar energy was used as a renewable thermal energy source, combined with a chemical potential gradient to drive the CO2 dissociation reaction. Continuous oxygen transfer across the membrane was achieved, and a novel solar chemical reactor design integrating a reactive ceria membrane was successfully demonstrated under real concentrated solar radiation, resulting in stable and unprecedented CO production rates.
CO2 single-step thermolysis was achieved using oxygen permeable MIEC (mixed ionic-electronic conducting) membranes made of ceria for separate production of CO on the feed side and O-2 on the sweep side. The CO2-dissociation reaction was driven by concentrated solar energy as a renewable thermal energy source and by applying a chemical potential gradient between both membrane sides. A continuous oxygen transfer across the membrane was achieved thanks to a flow of inert gas on the permeate side. This created the required oxygen partial pressure gradient and favored oxygen permeation via oxygen ion diffusion through the ceria membrane thickness. A novel solar chemical reactor integrating the reactive ceria membrane was designed and tested under real concentrated solar radiation, with operating temperatures up to 1550 degrees C. The reactive part of the tubular redox membrane was located inside a well-insulated cavity receiver for homogeneous heating, which was fed with a carrier argon flow on the sweep side to facilitate the transport and removal of the permeated oxygen. The dynamic response of the solar fuel production upon changing the operating conditions (temperature, CO2 mole fraction, and feed gas flow rate) in the membrane reactor was investigated by quantifying the evolved gas production rates. Continuous CO2 dissociation was achieved on the feed side inside the tubular membrane with in-situ spatial separation of O-2 and CO streams across the membrane. Reliable solar membrane reactor operation under real concentrated sunlight was successfully demonstrated for the first time, with stable and unprecedented CO production rates up to 0.071 mu mol/cm(2)/s at 1550 degrees C and CO/O-2 ratio of 2.
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