4.7 Article

Metal-organic framework-derived NiSe2-CoSe2@C/Ti3C2Tx composites as electromagnetic wave absorbers

Journal

CHEMICAL ENGINEERING JOURNAL
Volume 422, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2021.130079

Keywords

Ti3C2Tx; Selenization; Multilayer structure; Electromagnetic wave absorption

Funding

  1. National Natural Science Foundation of China [51407134]
  2. Natural Science Foundation of Shandong Province [ZR2019YQ24]
  3. Shandong Taishan Scholars Young Expert Program [tsqn202103057]
  4. China Postdoctoral Science Foundation [2016M590619]
  5. Natural Science Foundation of Heilongjiang Province [ZD2020E009]
  6. Qingchuang Talents Induction Program of Shandong Higher Education Institution (Research and Innovation Team of StructuralFunctional Polymer Composites)
  7. Thousand Talents Plan
  8. WorldClass University and Discipline
  9. Taishan Scholar's Advantageous and Distinctive Discipline Program of Shandong Province
  10. WorldClass Discipline Program of Shandong Province

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Two-dimensional metal carbide or nitride materials are considered as a new class of electromagnetic wave absorbing materials due to their unique multilayer structure and metal-like properties. The NiSe2-CoSe2@C/Ti3C2Tx composites show high electromagnetic wave absorption performance and have potential applications.
Two-dimensional metal carbide or nitride materials are considered as a new class of electromagnetic wave absorbing materials due to their unique multilayer structure and metal-like properties. The NiSe2-CoSe2@C/Ti3C2Tx composites were prepared through a facile hydrothermal treatment and selenization reaction. Distinctly, the maximum reflection loss (RL) is -60.46 dB with the mass fraction of NiSe2-CoSe2@C/Ti3C2Tx of 40 wt% at 2.6 mm. The bandwidth of RL < -10 dB reaches up to 5.68 GHz (10.32-16 GHz). The synergistic mechanism of the multiple scattering and multi-interface polarization effects of NiSe2-CoSe2@C compounded with Ti3C2Tx is reviewed to interpret the significant improvement of electromagnetic wave absorption performance. The results indicate that NiSe2-CoSe2@C/Ti3C2Tx composites have potential applications as realistic electromagnetic wave absorbing materials.

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