A simple strategy that may effectively tackle the anode-electrolyte interface issues in solid-state lithium metal batteries

Interface issues are the biggest challenges that hindering the commercialization of solid-state lithium metal batteries (SSLMBs). Here, we propose a novel strategy targeting for effectively resolving the tedious lithium-garnet solid electrolyte interface problem from the lithium side. We intentionally introduce alpha-MoO3 nanobelts into the molten metallic lithium, forming a Li-Mo composite. Compared to molten lithium, the composite improves wettability on the garnet electrolyte. As revealed by density functional theory calculations, such improvement could be ascribed to the reduced cohesive energy and the improved interface binding energy to the LLZTO. Intimate surface contact can be easily achieved without complicated surface treatment, which not only significantly reduces the interface resistance to similar to 1 Omega cm(2), but could also effectively inhibits the generation of lithium dendrites. These features ensure a significant critical current density of 1700 mu A cm(-2) and a stable electrochemical Li plating/stripping process for more than 1200 h. A full cell with the Li-Mo composite anode and LiFePO4 cathode also presents a fairly stable cycling performance at room temperature. Different from most previous strategies that try to tackle the interface issues from the electrolyte side, our research results suggest that designing lithium composite anodes with low cohesive energy and high interface binding energy to the solid electrolyte is an attractive and feasible solution to overcome interface problems.

Automated summary

The study proposed a novel strategy targeting interface issues in solid-state lithium metal batteries by introducing alpha-MoO3 nanobelts into molten metallic lithium to form a Li-Mo composite. This composite improved wettability on the garnet electrolyte, significantly reducing interface resistance and inhibiting the generation of lithium dendrites. The research results suggest that designing lithium composite anodes with low cohesive energy and high interface binding energy to the solid electrolyte is an attractive and feasible solution to overcome interface problems.