Self-assembled ZnO-carbon dots anode materials for high performance nickel-zinc alkaline batteries

The development of high-performance nickel-zinc (Ni-Zn) alkaline batteries is mainly plagued by short life span and poor rate performance of ZnO anode materials. To improve the cycling stability and rate capability of Ni-Zn batteries, carbon dots (CDs) are employed to construct clustered ZnO-CDs nanocomposites, coating ZnO with protective shells of carbon layers and providing electron paths to enhance conductivity of the nanocomposites. Univalent zinc species are found at the interfaces between CDs derivatives and ZnO, which are embedded in the nanoclusters and protected well by carbon coating. Theoretical calculations show univalent zinc species change the electronic structures of ZnO surface, so as to accelerate the charging process of ZnO anode materials. Such ZnO-CDs derived nanocomposites exhibit excellent rate capability (95.3%, 84.7% and 75.0% of capacity retention rate at 2, 5 and 10 A g(-1), respectively) and outstanding cycling stability with 92.0% of capacity retention rate after 5000 cycles, which is far better than ZnO based anodes without the protection of CDs (39.1% retention rate from 1 to 10 A g(-1) and 71.6% of capacity retention rate after 500 cycles).

Automated summary

The use of carbon dots to construct ZnO-CDs nanocomposites significantly improves the cycling stability and rate capability of Ni-Zn batteries, outperforming traditional ZnO-based anodes. This approach provides a promising strategy for enhancing the performance of alkaline batteries.