Journal
CHEMICAL ENGINEERING JOURNAL
Volume 429, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2021.132365
Keywords
Lignocellulose; Biomass; Conversion; Bulk chemicals; One-pot
Categories
Funding
- National Natural Science Foundation of China [32071716, 31870559, 31901262]
- Outstanding Youth Funding of National Forestry and Grassland Administration [20201326005]
- Outstanding Youth Funding of Fujian Agriculture and Forestry University [xjq201923]
Ask authors/readers for more resources
The article presents the development of one-pot oxidative and reductive processes for the high-yield conversion of lignocellulosic biomass to bulk chemicals. The cost analysis indicates the potential profitability of these processes in the petrochemical-dominated market.
Practical, high-yield conversion of lignocellulosic biomass to bulk chemicals is the goal of a profitable biorefinery. However, the development of current biorefining industries is highly restricted by process complexity and processing cost. In this article, we developed a one-pot oxidative process and a one-pot reductive process that allowed selective conversion of lignocellulosic biomass (e.g. hardwood) to multiple bulk chemicals such as monophenolics, diols, and organic acids in total yields of up to 96.8 wt%. Alkali was used to catalyze the disruption of biomass components via retro-aldol reactions to small active intermediate molecules, which were in-situ oxidized or reduced to stable products. As a result, monophenolics, which were derived from lignin, reached an unprecedented yield of 59.3 wt% (71.9 mol%, on the basis of lignin content). Organic acids also reached an unprecedented yield of 111.7 wt% (77.8 C%, on the basis of polysaccharide content). The diverse chemicals could meet broad needs of our society. Cost analysis indicates that the current processes could be profitable in the petrochemical-dominated market.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available