Journal
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION
Volume 170, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cep.2021.108695
Keywords
Reactive distillation; Vapor recompression; Heat integration; Process intensification
Categories
Funding
- SNGPL Chair of Gas Engineering at the Department of Chemical Engineering, University of Engineering & Technology, Lahore
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Research has shown that the energy consumption of a reactive distillation column can be significantly reduced by implementing external heat integration and a heat pump, thereby increasing the thermodynamic efficiency of the lactic acid production process. Energy savings in different configurations range from 63.4% to 64.9%, greatly reducing the total utilities requirement and decreasing the total annual cost.
Lactic acid is predominantly produced through microbial fermentation of renewable feedstocks. However, direct separation and purification of lactic acid from the fermentation broth is difficult. A two-step process involving (1) esterification of raw lactic acid with methanol to produce methyl lactate, and (2) hydrolysis of the methyl lactate to produce high-purity lactic acid, is commonly used. The hydrolysis step is typically carried out in a reactive distillation (RD) column to overcome equilibrium limitations by continuous removal of the product(s). However, the conventional RD process is highly energy intensive and has relatively low thermodynamic efficiency. We show that the energy requirement of the RD column can be significantly reduced by implementing external heat integration via a heat pump. Specifically, we show that a vapor-recompression-based reactive distillation (VRCRD) column offers up to 63.4% energy savings relative to the conventional RD column. The energy savings are further increased to 64.9% in a pre-compressor split (PCS-VRC-RD) configuration. This reduction in the total utilities requirement results in an increase in thermodynamic efficiency from 21.4% for the conventional RD column to 38.7% for the VRC-RD column and to 40.3% for the PCS-VRC-RD column. For a payback period of 5 years, these energy savings respectively correspond to 32.0% and 33.8% reduction in the total annual cost (TAC) relative to the conventional RD column.
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