Journal
CHEMICAL COMMUNICATIONS
Volume 58, Issue 12, Pages 1954-1957Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc06076g
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This study demonstrates the vapor-triggered crystal-to-crystal transformation between a discrete trinuclear complex and a two-dimensional coordination polymer. The transformation exhibits a coordination-induced spin state switch behavior attributed to the structural phase transition triggered by solvent signal, which can be detected reversibly through optical and magnetic responses.
Vapor-triggered crystal-to-crystal transformation between a discrete trinuclear complex [Ni-3(sih)(2)(py)(8)] and a two-dimensional (2D) coordination polymer [Ni-3(sih)(2)(py)(2)](n)center dot 2DMF center dot 2H(2)O was demonstrated. It provides an example of a solid-state coordination-induced spin state switch behavior attributed to the structural phase transition triggered by solvent signal. The reversible nature can be detected by both optical (spectral) and magnetic responses in cycles.
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