4.7 Article

Dynamic [1]rotaxanes via a reversible covalent bond and host-guest anion recognition

Journal

CHEMICAL COMMUNICATIONS
Volume 58, Issue 23, Pages 3815-3818

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc00779g

Keywords

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Funding

  1. Czech Science Foundation [20-13922S]
  2. CETOCOEN EXCELLENCE Teaming 2 project (MEYS CR) [CZ.02.1.01/0.0/0.0/17_043/0009632]
  3. RECETOX research infrastructure [LM2018121]
  4. project CZ-OPENSCREEN: National Infrastructure for Chemical Biology [LM2018130]

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Bambusuril-based [1]rotaxanes were formed quantitatively using a reversible covalent bond and host-guest anion recognition. These novel [1]rotaxanes exhibited a dynamic nature, facilitating carboxylate component exchange reactions in acetonitrile.
Bambus[6]uril-based [1]rotaxanes were formed quantitatively, utilizing a bis(acyloxy)iodate(i) reversible covalent bond and host-guest anion recognition. These novel [1]rotaxanes exhibited a dynamic nature facilitating carboxylate component exchange reactions in acetonitrile.

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