Journal
CHEMICAL COMMUNICATIONS
Volume 58, Issue 19, Pages 3101-3121Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc07040a
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Funding
- CNPq [PQ 309774/2020-9, 405052/2021-9]
- FAPEMIG [PPM-00635-18, RED-00282-16]
- Alexander von Humboldt Foundation (AvH)
- Royal Society of Chemistry [R19-9781]
- CAPES
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Metal catalyzed C-H functionalization is widely used in organic chemistry for selective functionalization. Understanding the synthesis of transition metal Cp-type catalysts is crucial for modifying the catalyst structure for different applications.
Metal catalyzed C-H functionalization offers a versatile platform for methodology development and a wide variety of reactions now exist for the chemo- and site-selective functionalization of organic molecules. Cyclopentadienyl-metal (CpM) complexes of transition metals and their correlative analogues have found widespread application in this area, and herein we highlight several key applications of commonly used transition-metal Cp-type catalysts. In addition, an understanding of transition metal Cp-type catalyst synthesis is important, particularly where modifications to the catalyst structure are required for different applications, and a summary of this aspect is given.
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