Journal
CHEMICAL COMMUNICATIONS
Volume 58, Issue 23, Pages 3799-3802Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc00342b
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Funding
- JSPS [18K14218, 17H06091]
- Grants-in-Aid for Scientific Research [17H06091, 18K14218] Funding Source: KAKEN
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The Pd-catalyzed transformation of N-phthaloyl hydrazones into nitriles involving the cleavage of an N-N bond is reported. The use of N-heterocyclic carbene as a ligand is crucial for the success of the reaction. N-Phthaloyl hydrazones prepared from aromatic aldehydes or cyclobutanones can be applied to this transformation, yielding aryl or alkenyl nitriles, respectively.
The Pd-catalyzed transformation of N-phthaloyl hydrazones into nitriles involving the cleavage of an N-N bond is reported. The use of N-heterocyclic carbene as a ligand is essential for the success of the reaction. N-Phthaloyl hydrazones prepared from aromatic aldehydes or cyclobutanones are applicable to this transformation, which gives aryl or alkenyl nitriles, respectively.
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