Journal
CHEMICAL COMMUNICATIONS
Volume 58, Issue 17, Pages 2866-2869Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc06983g
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Funding
- Agency for Medical Research and Development
- Japan Society for the Promotion of Science KAKENHI [JP 17H06448]
- JSPS Research Fellowships for Young Scientists
- MERIT program
- University of Tokyo
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Catalytic imino-ene-type allylation reactions of unactivated allyl compounds were achieved using a catalytic amount of a strongly basic mixed system. The reactions proceeded smoothly at low temperature, and notably, the gaseous alkene propylene could be used in this system.
Catalytic imino-ene-type allylation reactions of unactivated allyl compounds were achieved. In the presence of a catalytic amount of a strongly basic (KOBu)-Bu-t-LiTMP or (NaOBu)-Bu-t-LiTMP mixed system, the desired reactions proceeded smoothly at low temperature. Notably, a gaseous alkene, propylene, could also be used in this reaction system.
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