Journal
CHEMICAL COMMUNICATIONS
Volume 58, Issue 9, Pages 1306-1309Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc05724c
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Funding
- NSFC [91856126, 21778042]
- Scientific Research Grant of Ningbo University [215432000282]
- Ningbo Top Talent Project [215-432094250]
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A robust dearomative denitration method has been developed through a radical ipso-cyclization process, leading to the synthesis of valuable phosphonated or trifluoromethylated azaspiro[4.5]trienones with good functional group tolerance. This approach represents a convenient and powerful way to activate nitroarenes in a radical manner.
A robust dearomative denitration of nitroarene derivatives induced by a radical ipso-cyclization process has been developed, delivering valuable phosphonated or trifluoromethylated azaspiro[4.5]trienones with good functional group tolerance. This represents a convenient and powerful approach to activate nitroarenes in a radical manner.
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